Studies on Micellar Behaviour and Conductance of Zirconyl Soaps in Benzene-Methanol

Authors

  • M. ANIS Department of Chemistry, School of Chemical Sciences, St. John’s College, Agra – 282002, INDIA

Keywords:

Zirconyl soaps, CMC, conductivity, degree of dissociation and dissociation constant

Abstract

The critical micelle concentration (CMC), degree of dissociation and dissociation constant of the solutions of zirconyl soaps in benzene-methanol (4:1 v/v) mixture were determined from conductivity measurements. The results show that the zirconyl caprylate, caprate and laurate behave as a weak electrolyte in dilute solutions and the CMC was found to decrease with increasing chain length of fatty acid constituent of the soap molecule.

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References

J. matticlo, J. Protective and Decorative Coatings, Vol. 1, Wiley, New York (1941).

A.S.C. lawrence, J. Inst. Pet. Tech., 24, 207 (1938); 31, 303 (1945).

M. Arthur, Can. Patent, 1, 433, 433, March 05 (1946); Chem. Abstr. 40, 38479 (1946).

M. Goll, U.S. Patent, 2, 494, 941 Jan. 17 (1950); Chem. Abstr., 45, 303d (1951)

D.J. Bartleson and C.E. Hughes, U.S. Patent, 2, 560, 542, July 17 (1951); Chem. Abstr., 45, 8758f (1951).

R.W. Moncrieff, Textile Mfr., 89, 340 (1963).

B. Anilin and A.G. Soda Fabrik, Ger. Patent, 1, 152, 876. Aug. 14 (1963); Chem. Abstr., 59, 10308d (1963).

K. Worschech, P. Wedi and Loeffelhalz (Neynaber Chemie. GmbH) Ger. Often. 2, 941, 596 (C1 C08L 27/06), April 23 (1981); Appl. Oct. 13 (1979) 38 pp; Chem. Abstr., 95, 44210j (1981).

Hisida, Shingo, Japan Kokai Tokkyo Koho June 15 (1999) J.P. 11, 158, 292, Appl. 1997/324, 747, Nov. 26 (1997), 6 pp.

Satio, Satoyuski, Jpn. Kokai Tokkyo Koho Sep. 12 (2000) J.P. 248; Appl. 1999/53, 842, March 2 (1999).

Nagakoti, B.S. Jain, Sait, M.F. Addit. Pet. Refin. Pet, Prod. Fermulation Proc., 125-127 (1997).

K.N. Mehrotra, A. Kumar and S. Verghese, Tenside Surf. Det. 39(3), 25-27 (2002)

K.N. Mehrotra, K. Tandon and M.K. Rawat, Colloids and Surfaces, 57, 125-138 (1991).

K.N. Mehrotra and M. Anis, J . Am. Oil Chem. Soc., 74, 775-779 (1997).

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Published

2014-07-31

How to Cite

ANIS, M. . (2014). Studies on Micellar Behaviour and Conductance of Zirconyl Soaps in Benzene-Methanol. International Journal for Research in Applied Sciences and Biotechnology, 1(1), 15–18. Retrieved from https://ijrasb.com/index.php/ijrasb/article/view/46

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